Answer Save. All the carbonates of alkaline earth metal are more soluble in the presence of CO 2 due to the formation of corresponding bicarbonates. None of the carbonates is anything more than very sparingly soluble. Why does solubility of carbonates of alkaline earth metals decrease down the group? Solubility constant data for alkaline earth sulfate and carbonate phases were collated. ... (to a first approximation we might assume that the entropy change is constant for all the metals), solubility depends on both lattice energy and hydration enthalpy so you can't just look at one trend. The carbonates of alkaline earth metals also decompose on heating to form oxide and carbon dioxide. Lv 6. Relevance. Properties of Sulphates of Alkali Earth Metals. The carbonates tend to become less soluble as you go down the Group. However, the lattice energy remains almost unchanged. Your IP: 81.169.203.130 Answer. Be → Sr : form only monoxide(MO) Ba : form peroxide BaO2 under pressure; Solubility increases from BeO to BaO BeO,MgO,SrO,BaO → increasing solubility; All oxides are base (BeO is amphoteric) BeO,MgO,SrO,BaO Please enable Cookies and reload the page. Solubility of the carbonates. The carbonates decompose on heating form metal oxide and CO 2 . Hydroxides of the lighter alkaline earth metals are insoluble in water, but their solubility increases as the atomic number of the metal increases. Thus BeSO 4 and MgSO 4 are highly soluble, CaSO ­4 is sparingly soluble but the sulphates of Sr, Ba and Ra are virtually insoluble. Solubility constant data for alkaline earth sulfate and carbonate phases were collated. Cloudflare Ray ID: 6102f7b19c2c4c50 The stability of carbonates and bicarbonates increases down the group. The carbonates become less soluble down the group. Carbonates of metal: Thermal stabilityThe carbonates of alkali metals except lithium carbonate are stable to heat. sluggermatt15. alkali metals with those of the alkaline earth metals. We know that hydration energy and lattice energy are inversely proportional to the radii of the ions. Why does solubility of carbonates of alkaline earth metals decrease down the group? 900 0 C) The outermost shell has electrons which experience lesser nuclear charge as the radius goes on increasing. None of the carbonates is anything more than very sparingly soluble. The carbonates of group-2 metals and that of lithium decompose on heating, forming an oxide and carbon dioxide . (A) BaCO3 > SrCO3 > CaCO3 > MgCO3 (B) MgCO3 > CaCO3 > If you are at an office or shared network, you can ask the network administrator to run a scan across the network looking for misconfigured or infected devices. CaCO 3 + CO 2 + H 2 O —> Ca(HCO 3) 2 Lv 6. Arrange the alkaline earth metal carbonates in the decreasing order of thermal stability. Another way to prevent getting this page in the future is to use Privacy Pass. Solubilities of the halides, nitrates, carbonates, sulfates, and some perchlorates of all the alkali metals and alkaline earth metals in methanol at room temperature have been determined. Answer. 9 years ago. Nitrates – Group 1 and 2 elements are soluble in water because hydration energy is more than the lattice energy. Solubility of sodium carbonate and calcium carbonate are 30.7 g/100 g water and 0.0013/100 g respectively at 25 0 C. You can see the difference of values. The stability of carbonates and bicarbonates increases down the group. The sulphates of alkaline earth metals are all white solids. The solubility of carbonates of alkaline earth metal decreases down the group mainly due to decreasing hydration enthalpies of the cations from Be 2+ to Ba 2+ . Alkali metal carbonates, their thermal stability and solubility [duplicate] Ask Question Asked 3 years, 11 months ago. Compounds of alkaline earth metals. This group of elements includes beryllium, magnesium, calcium, strontium, barium, and radium.The elements of this group are quite similar in their physical and chemical properties. 3 Answers. Part 1. The alkaline earth metal oxides are formed from the thermal decomposition of the corresponding carbonates. If you are at an office or shared network, you can ask the network administrator to run a scan across the network looking for misconfigured or infected devices. However, carbonate of lithium, when heated, decomposes to form lithium oxide. Solubility of the carbonates. The carbonates tend to become less soluble as you go down the Group. None of the carbonates is anything more than very sparingly soluble. 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